Fluid Transport in Nanoporous Materials - W. Conner, engineering
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Fluid Transport in Nanoporous
Materials
edited by
Wm. Curtis Conner
Department of Chemical Engineering,
University of Massachusetts,
Amherst, MA, U.S.A.
and
Jacques Fraissard
Laboratoire de Physique Q uantique, ESPCI,
é
Universit Pierre et Marie Curie,
Paris, France
Published in cooperation with NATO Public Diplomacy Division
Proceedings of the NATO Advanced Study Institute on
Fluid Transport in Nanoporous Materials
La Colle sur Loup
,
France
16-28 June 2003
A C.I.P. Catalogue record for this book is available from the Library of Congress.
ISBN-10 1-4020-4380-5 (PB)
ISBN-13 978-1-4020-4380-2 (PB)
ISBN-10 1-4020-4378-3 (HB)
ISBN-13 978-1-4020-4378-9 (HB)
ISBN-10 1-4020-4382-1 (e-book)
ISBN-13 978-1-4020-4382-6 (e-book)
Published by Springer,
P.O. Box 17, 3300 AA Dordrecht, The Netherlands.
www.springer.com
Printed on acid-free paper
All Rights Reserved
© 2006 Springer
No part of this work may be reproduced, stored in a retrieval system, or transmitted
in any form or by any means, electronic, mechanical, photocopying, microfilming,
recording or otherwise, without written permission from the Publisher, with the exception
of any material supplied specifically for the purpose of being entered
and executed on a computer system, for exclusive use by the purchaser of the work.
Printed in the Netherlands.
TABLE OF CONTENTS
Preface .............................................................................................................. ix
T. Q. GARDNER, D. M. RUTHVEN
Nato-asi fluid transport in nanoporous materials course
…a student’s perspective and explanations from a veteran ................................. 1
D. M. RUTHVEN
Transport in microporous solids: an historical perpective
Part I: Fundamental Principles and Sorption Kinetics ........................................ 9
R. L. LAURENCE
Measurement of diffusion in macromolecular systems: solute diffusion in
polymers systems............................................................................................... 41
L. SARKISOV, K. F. CZAPLEWSKI, R. Q. SNURR
Role of diffusion in applications of novel nanoporous materials and in novel
uses of traditional materials ............................................................................... 69
H. RAMANAN, S. M. AUERBACH
Modeling jump diffusion in zeolites. I. Principles and methods ....................... 93
L. V. C. REES, L. SONG
Adsorption, thermodynamics and molecular simulations of cyclic
hydrocarbons in silicalite-1 and alpo
4
-5 zeolites ............................................. 125
D. M. RUTHEN
Transport in microporous solids
Part II: Measurement of micropore diffusivities............................................. 151
S. VASENKOV, J. KARGER
Structure-related anomalous diffusion in zeolites............................................ 187
W.C. CONNER
The contribution of surface diffusion to transport in nanoporous solids ......... 195
R. KRISHNA
The Maxwell-Stefan formulation of diffusion in zeolites................................ 211
vi
Table of Contents
R. H. ACOSTA, PETER BLÜMLER, H. W. SPIESS
Sensitivity and resolution in magnetic resonance imaging
of diffusive materials ....................................................................................... 241
V. SKIRDA, A. FILIPPOV, A. SAGIDULLIN A. MUTINA,
Restricted diffusion and molecular exchange processes in porous media as
studied by pulsed field gradient NMR ............................................................. 255
S. KENANE, C S. VASAM, P. P. KNOPS-GERRITS
Vibrational spectroscopy to monitor synthesis, adsorption and diffusion in
micro- and mesoporous metal phosphates ....................................................... 279
V.B. KAZANSKY
Nitrogen – oxygen diffusion in zeolites studied by drift ................................. 299
Xe NMR for diffusion of hydrocarbons in zeolites and
1
H NMR imaging
for competitive diffusion of binary mixtures of hydrocarbons in zeolites....... 315
H. JOBIC
Diffusion in zeolites measured by neutron scattering techniques................... 333
I.V. KOPTYUG, A.A. LYSOVA, A.V. MATVEEV, L.YU. ILYINA,
R.Z. SAGDEEV, V.N. PARMON
NMR imaging as a tool for studying mass transport in porous materials........ 353
S. VASENKOV, J. KARGER
PFG NMR diffusion studies of nanoporous materials ..................................... 375
L. V. C. REES, L. SONG
Diffusion of cyclic hydrocarbons in zeolites by frequency-response and
molecular simulation methods ......................................................................... 383
J.-P. KORB
Surface diffusion of liquids in disordered nanopores and materials: a field
cycling relaxometry approach.......................................................................... 415
A. M. MENDES, F. D. MAGALHÃES, C. A.V. COSTA
New trends on membrane science.................................................................... 439
R. ARCHIPOV, G. PIMENOV
M.-A. SPRINGUEL-HUET
129
Table of Contents
vii
V. I. VOLKOV, E. V. VOLKOV, S. L. VASILYAK, Y.S. HONG,
The ionic and molecular transport in polymeric and biological
membranes on magnetic resonance data.......................................................... 481
Molecular modeling: A complement to experiment in material
research for non cryogenic gas separation technologies ................................ 509
S. M. AUERBACH
Modeling jump diffusion in zeolites. Part II: Applications ............................. 535
Posters Communications
Y.I. ARISTOV, I.S. GLAZNEV, L.G. GORDEEVA, I.V. KOPTYUG,
L.YU. ILYINA, J. KÄRGER, C. KRAUSE, B. DAWOUD
Dynamics of water sorption on composites “cacl
2
in silica”: single grain,
granulated bed, consolidated layer................................................................... 553
F. BENALIOUCHE, Y. BOUCHEFFA, P. MAGNOUS
Effect of carbonaceous compounds on diffusion of alkanes in 5A zeolite ...... 567
C. CHMELIK, E. LEHMANN, S. VASENKOV, B. STAUDTE,
J. KÄRGER
Application of interference and IR microscopy for studies
of intracrystalline molecular transport in AFI type zeolites ............................ 575
G. Di FEDERICO, I. CAMPLONE, S. BRANDINI, J. BARKER
Coal characterization for carbon dioxide sequestration purposes.................... 583
V. T. HOANG , Q. HUANG , M. EIC, T. O. DO , S. KALIAGUINE
Effect of the intrawall microporosity on the diffusion characterization
of bi-porous SBA-15 materials ........................................................................ 591
I.A. HADJIAGAPIOU, A. MALAKIS, S. S. MARTINOS
Structure of a single-species-fluid in a spherical pore ..................................... 603
S. LAGORSSE PONTES, F. D. MAGALHÃES, A. MENDES
Carbon molecular sieve membranes: Characterisation
and application to xenon recycling .................................................................. 613
C.H. CLEE
P. PULLUMBI
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